Material Safety Data Sheet
WHMIS (Pictograms) WHMIS (Classification) Protective Clothing TDG (pictograms)
Not controlled
Section 1. Chemical Product and Company Identification
Not available.
Product Name Code
SPRAY OIL 13E
Validated on 9/16/2003.
Not available.
Synonym
Petro-Canada: 403-296-3000
In case of
PETRO-CANADA
Manufacturer
Emergency Canutec Transportation:
P.O. Box 2844
613-996-6666
Calgary, Alberta
Poison Control Centre: Consult
T2P 3E3
local telephone directory for
Emulsified Spray Oils are severely hydrotreated mineral oils with added
Material Uses emergency number(s).
emulsifier, used as dormant oils or as a carrier for formulated agricultural
insecticide spray.
Section 2. Composition and Information on Ingredients
Exposure Limits (ACGIH)
CAS # % (V/V) TLV-TWA(8 h) STEL CEILING
Name
1) Mixture of severely hydrotreated and hydrocracked base Mixture 100 5 mg/m鲁 (oil mist) 10 mg/m鲁 (oil Not established
mist)
oil (petroleum) and other proprietary, non-hazardous
additives.
Not applicable
Manufacturer
Recommendation
Consult local, state, provincial or territory authorities for acceptable exposure limits.
Other Exposure
Limits
Section 3. Hazards Identification.
Non irritating to slight transient irritation to skin and eyes, but no permanent damage. Relatively non-toxic via ingestion.
Potential Health
This product has a low vapour pressure and is not expected to present an inhalation exposure at ambient conditions.
Effects
Upon heating to high temperatures, or mechanical actions which may produce vapours or mists, inhalation of product may
cause irritation of the breathing passages. For more information, refer to Section 11.
Section 4. First Aid Measures
IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention.
Eye Contact
Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running
Skin Contact
water and non-abrasive soap. Seek medical attention.
Evacuate the victim to a safe area as soon as possible. If the victim is not breathing, perform artificial respiration. Allow
Inhalation
the victim to rest in a well ventilated area. Seek medical attention.
DO NOT induce vomiting because of danger of aspirating liquid into lungs. Seek medical attention.
Ingestion
Not available
Note to Physician
Section 5. Fire-fighting Measures
May be combustible at high temperature. Not available.
Flammability Flammable Limits
OPEN CUP: 174掳C (345.2掳F) (Cleveland) Not available.
Flash Points Auto-Ignition
Temperature
Low fire hazard. This material must be heated Explosion Containers may explode in heat of fire. Do not
Fire Hazards
before ignition will occur. cut, weld, heat, drill or pressurize empty
in Presence of Hazards in
container.
Various Presence of
Substances Various
Substances
Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete combustion.
Products of
Combustion
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PURESPRAY FOLIAR 13E Page Number: 2
NAERG96, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a fire, ISOLATE
Fire Fighting
for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5 mile) in all directions. Shut
Media and
off fuel to fire if it is possible to do so without hazard. If this is impossible, withdraw from area and let fire burn out under
Instructions
controlled conditions. Withdraw immediately in case of rising sound from venting safety device or any discolouration of
tank due to fire. Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion.
SMALL FIRE: use DRY chemicals, foam, water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small
outdoor fires, portable fire extinguishers may be used, and self contained breathing apparatus (SCBA) may not be
required. For all indoor fires and any significant outdoor fires, SCBA is required. Respiratory and eye protection are
required for fire fighting personnel.
Section 6. Accidental Release Measures
NAERG96, GUIDE 171, Substances (low to moderate hazard). ELIMINATE ALL IGNITION SOURCES. Avoid contact.
Material Release
Stop leak if without risk. Contain spill. Absorb with inert absorbents, dry clay, or diatomaceous earth. Avoid inhaling dust
or Spill
of diatomaceous earth for it may contain silica in very fine particle size, making this a potential respiratory hazard. Place
used absorbent in closed metal containers for later disposal or burn absorbent in a suitable combustion chamber. DO
NOT FLUSH TO SEWERS, STREAMS OR OTHER BODIES OF WATER. Check with applicable jurisdiction for specific
disposal requirements of spilled material and empty containers. Notify the appropriate authorities immediately.
Section 7. Handling and Storage
Avoid inhalation and skin contact especially when handling used oil. Keep away from sources of ignition. DO NOT reuse
Handling
empty containers without commercial cleaning or reconditioning. Practice good personal hygiene. Wash hands after
handling and before eating. Launder work clothes frequently. Discard saturated leather goods.
Store in tightly closed containers in cool, dry, isolated, well-ventilated area, and away from incompatibles.
Storage
Section 8. Exposure Controls/Personal Protection
Engineering Controls For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limit. Make-up air should always be supplied to balance air
removed by exhaust ventilation. Ensure that eyewash station and safety shower are close to work-station.
Personal Protection - The selection of personal protective equipment varies, depending upon conditions of use.
Eyes Eye protection (i.e., safety glasses, safety goggles and/or face shield) should be determined based on conditions of use. If
product is used in an application where splashing may occur, the use of safety goggles and/or a face shield should be
considered.
Body Wear appropriate clothing to prevent skin contact. As a minimum long sleeves and trousers should be worn.
Respiratory Where concentrations in air may exceed the occupational exposure limits given in Section 2 (and those applicable to your
area) and where engineering, work practices or other means of exposure reduction are not adequate, NIOSH approved
respirators may be necessary to prevent overexposure by inhalation.
Hands Wear appropriate chemically protective gloves. When handling hot product ensure gloves are heat resistant and
insulated.
Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin.
Section 9. Physical and Chemical Properties
Viscous liquid. 13.6 cSt @ 40掳C (104掳F), 3.18 cSt @ 100掳C
Physical State and Viscosity
(212掳F)
Appearance
Colourless to light yellow. -18掳C
Colour Pour Point
No odour or slight petroleum oil like. Not applicable.
Odour Softening Point
Not available. Not applicable.
Odour Threshold Dropping Point
Not available. Not applicable.
Boiling Point Penetration
0.8545 kg/L @ 15掳C (59掳F). Not available.
Density Oil / Water Dist.
Coefficient
Not available. Not available
Vapour Density Ionicity (in water)
Negligible at ambient temperature and Dispersion Properties Not available.
Vapour Pressure
pressure.
Non-volatile. Insoluble in water.
Volatility Solubility
Section 10. Stability and Reactivity
Not available.
Corrosivity
The product is stable under normal handling Hazardous Will not occur under normal working conditions.
Stability
and storage conditions. Polymerization
Reactive with oxidizing agents and reducing Decomposition May release COx, smoke and irritating vapours
Incompatible
agents. when heated to decomposition.
Substances / Products
Conditions to Avoid
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PURESPRAY FOLIAR 13E Page Number: 3
Section 11. Toxicological Information
Skin contact, eye contact, inhalation and ingestion.
Routes of Entry
Based on toxicity of components.
Acute Lethality
Acute oral toxicity (LD50): >5000 mg/kg (rat).
Acute dermal toxicity (LD50): >2000 mg/kg (rabbit).
Acute inhalation toxicity (LC50): >2500 mg/m鲁/4h (rat).
Chronic or Other Toxic Effects
Dermal Route: Prolonged or repeated contact may cause skin irritation characterized by dermatitis or oil acne.
Inhalation Route: Negligible breathing hazard at normal temperatures (up to 38掳C) or recommended blending temperatures.
Elevated temperatures or mechanical action may form vapours, mists or fumes. Inhalation of oil mists or
vapours from hot oil may cause irritation of the upper respiratory tract.
Oral Route: Low toxicity; has laxative effect.
Eye Irritation/Inflammation: Repeated or prolonged contact may cause transient irritation, but no permanent damage.
Immunotoxicity: Not available.
Skin Sensitization: This product may be a skin sensitizer in some individuals.
Respiratory Tract Sensitization: This product is not expected to be a respiratory tract sensitizer, based on the available data and the known
hazards of the components.
Mutagenic: Based on actual test results of base oils and results of similar products, severely hydrotreated base oils give
negative results when tested for: (a) Salmonella Typhimurium TA98 using the Modified Ames Assay for
Petroleum Product; (b) Salmonella-Escherichia coli/Mammalian-Microsome Reverse Mutation Assay (Ames
test) with a Confirmatory Assay; (c) Structural Chromosomal Aberrations in Chinese Hamster Ovary (CHO)
Cells.
Reproductive Toxicity: This product is not considered to be a reproductive hazard, based on the available data and the known
hazards of the components.
Teratogenicity/Embryotoxicity: This product is not considered to be a teratogen or an embryotoxin, based on the available data and the
known hazards of the components.
Carcinogenicity (ACGIH): This product is not known to contain any chemicals at reportable quantities that are listed as A1 or A2
carcinogens by ACGIH.
Carcinogenicity (IARC): This product is not known to contain any chemicals at reportable quantities that are listed as group 1, 2A or 2B
carcinogens by IARC.
Carcinogenicity (NTP): This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by
NTP.
Carcinogenicity (IRIS): Not available.
Carcinogenicity (OSHA): This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by
OSHA.
No additional remark.
Other Considerations
Section 12. Ecological Information
Persistance/
Not available Not available
Environmental
Bioaccumulation
Fate
Potential
Not available. Not available.
BOD5 and COD Products of
Biodegradation
No additional remark.
Additional Remarks
Section 13. Disposal Considerations
Spent/used/waste oil may meet the requirements of a hazardous waste. Consult your local or regional authorities.
Waste Disposal
Preferred waste management priorities are: (1) recycle or reprocess; (2) incineration with energy recovery; (3) disposal at
licensed waste disposal facility. Ensure that disposal or reprocessing is in compliance with government requirements and
local disposal regulations.
Section 14. Transport Information
Not controlled under TDG (Canada). Not applicable.
TDG Classification Special Provisions
for Transport
Continued on Next Page Available in French
PURESPRAY FOLIAR 13E Page Number: 4
Section 15. Regulatory Information
A component of this product is not listed on the Canadian Domestic Substances List (DSL).
Other
Regulations
All components of this formulation are listed on the US EPA-TSCA Inventory.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all of the information required by the CPR.
Please contact Product Safety for more information.
For European information please contact Not controlled under the HCS (United States).
DSD/DPD (Europe) HCS (U.S.A.)
Product Safety.
ADR (Europe) DOT (U.S.A)
NOT EVALUATED FOR
EUROPEAN TRANSPORT
(Pictograms) (Pictograms)
NON 脡VALU脡 POUR LE
TRANSPORT EUROP脡EN.
Rating
Health Hazard 1 0 Insignificant
HMIS (U.S.A.) NFPA (U.S.A.) 1 Fire Hazard
1 Slight
Fire Hazard 1 Health 1 0 Reactivity 2 Moderate
Reactivity 0 3 High
Specific hazard
Personal Protection B 4 Extreme
Section 16. Other Information
Available upon request.
References
* Marque de commerce de Petro-Canada - Trademark
Glossary
ACGIH - American Conference of Governmental Industrial Hygienists IRIS - Integrated Risk Information System
ADR - Agreement on Dangerous goods by Road (Europe) LD50/LC50 - Lethal Dose/Concentration kill 50%
ASTM - American Society for Testing and Materials ( LDLo/LCLo - Lowest Published Lethal Dose/Concentration
BOD5 - Biological Oxygen Demand in 5 days NAERG'96 - North American Emergency Response Guide Book (1996)
CAN/CGA B149.2 Propane Installation Code NFPA - National Fire Prevention Association
CAS - Chemical Abstract Services NIOSH - National Institute for Occupational Safety & Health
CEPA - Canadian Environmental Protection Act NPRI - National Pollutant Release Inventory
CERCLA - Comprehensive Environmental Response, Compensation and Liability NSNR - New Substances Notification Regulations (Canada)
Act NTP - National Toxicology Program
CFR - Code of Federal Regulations OSHA - Occupational Safety & Health Administration
CHIP - Chemicals Hazard Information and Packaging Approved Supply List PEL - Permissible Exposure Limit
COD5 - Chemical Oxygen Demand in 5 days RCRA - Resource Conservation and Recovery Act
CPR - Controlled Products Regulations SARA - Superfund Amendments and Reorganization Act
DOT - Department of Transport SD - Single Dose
DSCL - Dangerous Substances Classification and Labeling (Europe) STEL - Short Term Exposure Limit (15 minutes)
DSD/DPD - Dangerous Substances or Dangerous Preparations Directives TDG - Transportation Dangerous Goods (Canada)
(Europe) TDLo/TCLo - Lowest Published Toxic Dose/Concentration
DSL - Domestic Substance List TLm - Median Tolerance Limit
EEC/EU - European Economic Community/European Union TLV-TWA - Threshold Limit Value-Time Weighted Average
EINECS - European Inventory of Existing Commercial Chemical Substances TSCA - Toxic Substances Control Act
EPCRA - Emergency Planning and Community Right to Know Act USEPA - United States Environmental Protection Agency
FDA - Food and Drug Administration USP - United States Pharmacopoeia
FIFRA - Federal Insecticide, Fungicide and Rodenticide Act WHMIS - Workplace Hazardous Material Information System
HCS - Hazardous Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
Prepared by Product Safety - JDW on 9/16/2003.
For Copy of MSDS
Lubricants: Data entry by Product Safety - JDW.
Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564
Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax:
1-800-201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 800-201-6285
For Product Safety Information: (905) 804-4752
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of
its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards
that exist.
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